Enantioselective Cascade Cyclization/Protodemetalation of Polyenes with N3Pt2+ Catalysts
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چکیده
منابع مشابه
Enantioselective Cascade Cyclization/Protodemetalation of Polyenes with N3Pt2+ Catalysts
The combination of the N-based pincer ligand PyBOX with Pt2+ leads to new catalysts for the enantioselective cycloisomerization of dienyl- and trienyl-ols. The mechanistic combination of electrophilic cyclization followed by rapid protodemetalation is surprising and leads to a powerful construct for developing new reactions.
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ژورنال
عنوان ژورنال: ACS Catalysis
سال: 2014
ISSN: 2155-5435,2155-5435
DOI: 10.1021/cs401190c